7212334-00 HYJET IV-A PLUS MATERIAL SAFETY DATA BULLETIN --------------------------------------------------------------------------- -------------------------------------------------------------------------- 1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------- PRODUCT NAME: HYJET IV-A PLUS SUPPLIER: EXXON MOBIL CORPORATION 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Health and Safety Emergency (call collect): 609-737-4411 24 - Hour Transportation Emergency (Primary) CHEMTREC: 800-424-9300 (Secondary) 281-834-3296 Product and Technical Information: 800-443-9966 MSDS Fax on Demand: 613-228-1467, other MSDS information: 856-224-4644 -------------------------------------------------------------------------- 2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------- CHEMICAL NAMES AND SYNONYMS: SYNTHETIC BASE STOCKS AND ADDITIVES GLOBALLY REPORTABLE MSDS INGREDIENTS: Substance Name Approx. Wt% -------------- ----------- TRIBUTYL PHOSPHATE 70-80 (126-73-8) ALIPHATIC EPOXIDE 5-15 COMPONENT(S) OF PRODUCT INGREDIENTS INCLUDE: TRIPHENYL PHOSPHATE 4 (115-86-6) See Section 8 for exposure limits (if applicable). -------------------------------------------------------------------------- 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------- This product is considered hazardous according to regulatory guidelines (See Section 15). EMERGENCY OVERVIEW: Clear Purple Liquid. DOT ERG No. : 171 POTENTIAL HEALTH EFFECTS: Strong eye irritation. Skin irritation. May be harmful if swallowed. POTENTIAL HAZARDS OUTSIDE OF NORMAL USE CONDITIONS: Product may decompose at elevated temperatures or under fire conditions and give off irritating, noxious and toxic vapors/fumes. Symptoms from acute exposure in confined spaces may include headache, nausea, eye, nose and throat irritation. With prolonged exposure, serious health consequences such as lung damage and death may occur if exposures are allowed to continue without proper respiratory protection. Minimize breathing vapor/fume/smoke. For further health effects/toxicological data, see Section 11. -------------------------------------------------------------------------- 4. FIRST AID MEASURES -------------------------------------------------------------------------- EYE CONTACT: Flush thoroughly with water for at least 15 minutes. Get immediate medical assistance. If medical assistance is not immediately available, flush an additional 15 minutes. Instill local anesthetic eyedrops to facilitate irrigation, if available. SKIN CONTACT: Remove contaminated clothing. Wash contact areas with soap and water. Launder contaminated clothing before reuse. INHALATION: Remove from further exposure. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with bag-valve-mask device or use mouth-to-mouth resuscitation. INGESTION: Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIANS: Material if aspirated into the lungs may cause chemical pneumonitis. Treat appropriately. -------------------------------------------------------------------------- 5. FIRE-FIGHTING MEASURES -------------------------------------------------------------------------- EXTINGUISHING MEDIA: Not applicable. SPECIAL FIRE FIGHTING PROCEDURES: Minimize breathing of gases, vapors, fumes, or decomposition products. Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. Flash Point C(F): 178(352) (ASTM D-92). Flammable Limits (approx.% vol.in air) - LEL: NE, UEL: NE NFPA HAZARD ID: Health: 2, Flammability: 1, Reactivity: 0 -------------------------------------------------------------------------- 6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------- NOTIFICATION PROCEDURES: Report spills as required to appropriate authorities. U. S. Coast Guard regulations require immediate reporting of spills that could reach any waterway including intermittent dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant treated sawdust, diatomaceous earth, etc. Scrape up and remove. Dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. Personnel performing cleanup must use protective equipment. ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and contact with soil. PERSONAL PRECAUTIONS: See Section 8 -------------------------------------------------------------------------- 7. HANDLING AND STORAGE -------------------------------------------------------------------------- HANDLING: Avoid contact with eyes. Avoid prolonged repeated skin contact. Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner in accordance with governmental regulations. STORAGE: Do not store in open or unlabelled containers. Store away from strong oxidizing agents or combustible material. EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. -------------------------------------------------------------------------- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------- OCCUPATIONAL EXPOSURE LIMITS: When mists/aerosols can occur, the following are recommended: 5 mg/m3 (as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist) - ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA Permissible Exposure Limit (PEL) ---TWA--- ----STEL--- NOTE Substance Name (CAS-No.) Source ppm mg/m3 ppm mg/m3 ------ --- ----- --- ----- ---- TRIBUTYL PHOSPHATE (126-73-8) OSHA 0.2 2.5 ACGIH 0.2 2.2 TRIPHENYL PHOSPHATE (115-86-6) OSHA 3 ACGIH 3 NOTE: Limits shown for guidance only. Follow applicable regulations. VENTILATION: Use in well ventilated area. RESPIRATORY PROTECTION: None under normal use conditions. Approved supplied-air respirators should be used when exposed to vapors from heated material. EYE PROTECTION: Chemical type goggles must be worn. SKIN PROTECTION: Impervious gloves should be worn. -------------------------------------------------------------------------- 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------- Typical physical properties are given below. Consult Product Data Sheet for specific details. APPEARANCE: Liquid COLOR: Clear Purple ODOR: Sweet ODOR THRESHOLD-ppm: NE pH: NE BOILING POINT C(F): 288(550) MELTING POINT C(F): NA FLASH POINT C(F): 178(352) (ASTM D-92) FLAMMABILITY (solids): NE AUTO FLAMMABILITY: NE EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: 0.5 VAPOR DENSITY: NE EVAPORATION RATE: NE RELATIVE DENSITY, 15/4 C: 0.995 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: NE VISCOSITY AT 40 C, cSt: 10.3 VISCOSITY AT 100 C, cSt: NE POUR POINT C(F): -57(-70) FREEZING POINT C(F): NE VOLATILE ORGANIC COMPOUND: NE NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE -------------------------------------------------------------------------- 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------- STABILITY (THERMAL, LIGHT, ETC.): Stable. CONDITIONS TO AVOID: Extreme heat. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Phosphorus oxides. Sulfur oxides and H2S. Nitrogen oxides. Aldehydes. Smoke. HAZARDOUS POLYMERIZATION: Will not occur. -------------------------------------------------------------------------- 11. TOXICOLOGICAL DATA -------------------------------------------------------------------------- ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Harmful (LD50: greater than 200 but 2000 mg/kg or less). ---Based on testing of similar products and/or the components. DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Not established EYE IRRITATION (RABBITS): Strong irritant. (Draize score: greater than 35 but 55 or less). ---Based on testing of similar products and/or the components. SKIN IRRITATION (RABBITS): Irritant. (Primary Irritation Index: 3 or greater but less than 5). ---Based on testing of similar products and/or the components. OTHER ACUTE TOXICITY DATA: Vapors and/or aerosols which may be formed at elevated temperatures may be irritating to eyes and respiratory tract. ---NEUROTOXICOLOGY (SUMMARY)--- This product contains tributyl phosphate (TBP), which when give in large oral doses (4 g/kg) to hens caused delayed nerve damage that resulted in loss of coordination and difficulty in walking. These effects were not observed in hens give 2 g/kg. In another study, hens given 3 g/kg also showed no effects. continuous daily dermal exposure to 50 mg/kg of this material for 5 days/week for 4 months similarly did not result in any nerve damage in hens. Evaluations of the manufacturer's workers who make this and similar chemicals have not demonstrated any unusual pattern of mortality or disease. There should be no risk of nerve damage to workers who handle this product when the precautions outlined are followed to minimize exposure. ---CHRONIC TOXICOLOGY (SUMMARY)--- Tributyl phosphate has been shown to be neither a mutagen nor a clastogen in genotoxicity studies conducted in vivo and in vitro. In a long term feeding study in mice (18 month), TBP caused an increased incidence of benign liver tumors in male CD-1 mice (high dose only, 3500 ppm; NOEL 1000 ppm). No tumors were observed in female mice in this study. In male and female CD rats, a chronic feeding study (24 month) resulted in benign and malignant tumors of the urinary bladder in both sexes at 700 and 3000 ppm. The combined data from the rat and mouse long term feeding studies suggest a possible risk of irreversible effects from TBP. However, a recent mechanistic study in rats conducted with TBP suggests that the urinary bladder hyperplasia produced by TBP may be reversible. An independent risk assessment concluded that exposure to TBP during routine workplace handling and industrial exposure by all routes will not increase the risk of bladder cancer among exposed individuals. -------------------------------------------------------------------------- 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------- ENVIRONMENTAL FATE AND EFFECTS: This material is expected to be toxic to aquatic organisms, based on the components. -------------------------------------------------------------------------- 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------- WASTE DISPOSAL: Dispose of waste by supervised incineration in compliance with applicable laws and regulations. Dispose of waste at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity. The unused product is not formulated with substances covered by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. -------------------------------------------------------------------------- 14. TRANSPORT INFORMATION -------------------------------------------------------------------------- USA DOT: SHIPPING NAME: Environmentally Hazardous Substances, Liquid, n.o.s. (contains TRIBUTYL PHOSPHATE) HAZARD CLASS & DIV: 9 ID NUMBER: UN3082 ERG NUMBER: 171 PACKING GROUP: PG III STCC: NE DANGEROUS WHEN WET: No POISON: No LABEL(s): Class 9, Marine Pollutant PLACARD(s): Class 9 PRODUCT RQ: NA MARPOL III STATUS: NA IMO: HAZARD CLASS & DIV: 9 UN NUMBER: 3082 PACKING GROUP: PG III SHIPPING NAME: Environmentally Hazardous Substances, Liquid, n.o.s. (contains TRIBUTYL PHOSPHATE) LABEL(s): Class 9, Marine Pollutant MARPOL III STATUS: NA ICAO/IATA: HAZARD CLASS & DIV: 9 ID/UN Number: 3082 PACKING GROUP: PG III SHIPPING NAME: Environmentally Hazardous Substances, Liquid, n.o.s. (contains TRIBUTYL PHOSPHATE) SUBSIDIARY RISK: NA LABEL(s): Class 9, Marine Pollutant -------------------------------------------------------------------------- 15. REGULATORY INFORMATION -------------------------------------------------------------------------- US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with OSHA 29 CFR 1910.1200 and determined to be hazardous. EU Labeling: Product is dangerous as defined by the European Union Dangerous Substances/Preparations Directives. Symbol: Xn Harmful. Risk Phrase(s): R22-36/38. Harmful if swallowed. Irritating to eyes and skin. Safety Phrase(s): S24/25-62. Avoid contact with skin and eyes. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contains: Organic Acid Phosphates. Governmental Inventory Status: All components comply with TSCA. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: CHRONIC ACUTE This product contains no chemicals subject to the supplier notification requirements of SARA (313) toxic release program. The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS ------------- ---------- -------------- TRIPHENYL PHOSPHATE (COMPONENT 115-86-6 1, 10, 18, 19, 20, ANALYSIS) (3.50%) 21, 22, 23, 25, 26 TRIBUTYL PHOSPHATE 126-73-8 1, 10, 18, 19, 20, 21, 23, 25, 26 --- REGULATORY LISTS SEARCHED --- 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK 26=RI RTK Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive -------------------------------------------------------------------------- 16. OTHER INFORMATION -------------------------------------------------------------------------- USE: AVIATION HYDRAULIC FLUID NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES ARE NOT FORMULATED TO CONTAIN PCBS. Health studies have shown that many hydrocarbons pose potential human health risks which may vary from person to person. Information provided on this MSDS reflects intended use. This product should not be used for other applications. In any case, the following advice should be considered: INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. Precautionary Label Text: CONTAINS TRIBUTYL PHOSPHATE WARNING! CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. PROLONGED, REPEATED SKIN CONTACT MAY CAUSE IRRITATION. Avoid contact with eyes. Avoid contact with skin. Do not take internally. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. In case of contact, wash skin with soap and water. Remove contaminated clothing. Wash clothing before reuse. If swallowed, seek immediate medical attention. If respiratory irritation, cough, shortness of breath, wheezing or chest tightness occurs, remove from further exposure and get immediate medical assistance. For industrial use only. ------------------------------------------------------------------------- ************************************************************************* For Internal Use Only: MHC: 2* 1* NE 3* 2*, MPPEC: D, TRN: 7212334-00, CMCS97: 97P282, REQ: MIAMI, SAFE USE: L EHS Approval Date: 27SEP2001 ************************************************************************* ************************************************************************* Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Exxon Mobil Corporation and its affiliated companies assume no responsibility for accuracy of information unless the document is the most current available from an official ExxonMobil distribution system. Exxon Mobil Corporation and its affiliated companies neither represent nor warrant that the format, content or product formulas contained in this document comply with the laws of any other country except the United States of America. ************************************************************************* Copyright 2001 Exxon Mobil Corporation, All rights reserved