MATERIAL SAFETY DATA SHEET Revision Date: 04/20/2004 -------------------------------------------------------------------------------- SECTION 1 PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------------- PRODUCT: AEROSHELL® Turbine Oil 560 MSDS NUMBER: 857485E - 3 PRODUCT CODE(S): 60074 MANUFACTURER ADDRESS:SOPUS Products, P.O. Box 4453, Houston, TX. 77210-4453 TELEPHONE NUMBERS Spill Information: (877) 242-7400 Health Information: (877) 504-9351 MSDS Assistance Number: (877) 276-7285 -------------------------------------------------------------------------------- SECTION 2 PRODUCT/INGREDIENTS -------------------------------------------------------------------------------- CAS# CONCENTRATION INGREDIENTS Aviation Turbine Oil Mixture 90 - 98.99 %weight Synthetic ester blend with pentaerythritol 90-30-2 1 - 2.99 %weight N-Phenyl-Naphthalenamine 1330-78-5 1 - 2.99 %weight Tricresyl phosphate (mixed isomers) Mixture < 1 %weight Proprietary additives -------------------------------------------------------------------------------- SECTION 3 HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- EMERGENCY OVERVIEW Appearance & Odor: Light brown liquid. Mild odor. Health Hazards: May be harmful if absorbed through the skin. May be harmful if swallowed. Physical Hazards: No known physical hazards. NFPA Rating (Health, Fire, Reactivity): 1, 1, 0 Hazard Rating:Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 Inhalation: In applications where vapors (caused by high temperature) or mists (caused by mixing or spraying) are created, breathing may cause a mild burning sensation in the nose, throat and lungs. Eye Irritation: May be irritating to the eyes causing a burning sensation, redness, swelling and/or blurred vision. Skin Contact: Slightly toxic and may be harmful if absorbed through the skin. May be irritating to the skin causing a burning sensation, redness and/or swelling. Ingestion: May be harmful if swallowed. Other Health Effects: Refer to Section 11, Toxicological Information, for specific information on the following effects: Reproductive Toxicity For additional health information, refer to section 11. -------------------------------------------------------------------------------- SECTION 4 FIRST AID MEASURES -------------------------------------------------------------------------------- Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue breathing or CPR as required and transport to the nearest medical facility. Skin: Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment. Eye: Flush eyes with large amounts of water for at least 15 minutes. If redness, burning, blurred vision or swelling persist, transport to nearest medical facility for additional treatment. Ingestion: DO NOT induce vomiting. DO NOT take internally. Have victim rinse mouth out with water, then drink sips of water to remove taste from mouth. If the victim is coughing, choking, has shortness of breath, or difficulty breathing, transport to the nearest medical facility for additional treatment. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F, shortness of breath, chest congestion or continued coughing or wheezing. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. -------------------------------------------------------------------------------- SECTION 5 FIRE FIGHTING MEASURES -------------------------------------------------------------------------------- Flash Point [Method]: >490 ºF/>254.44 ºC [ Cleveland Open Cup] Extinguishing Media: Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of water. Fire Fighting Instructions: Material will not burn unless preheated. Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots), including a positive pressure, NIOSH approved, self-contained breathing apparatus. -------------------------------------------------------------------------------- SECTION 6 ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------------- Protective Measures: May burn although not readily ignitable. Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8. Spill Management: FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper disposal. Reporting: CERCLA: Product is covered by EPA's Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) petroleum exclusion. Releases to air, land, or water are not reportable under CERCLA (Superfund). CWA: This product is an oil as defined under Section 311 of EPA's Clean Water Act (CWA). Spills into or leading to surface waters that cause a sheen must be reported to the National Response Center, 1-800-424-8802. -------------------------------------------------------------------------------- SECTION 7 HANDLING AND STORAGE -------------------------------------------------------------------------------- Precautionary Measures: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet. Launder contaminated clothing before reuse. Properly dispose of contaminated leather articles such as shoes or belts that cannot be decontaminated. Do not take internally. Do not taste or swallow. Avoid heat, open flames, including pilot lights, and strong oxidizing agents. Use explosion-proof ventilation to prevent vapor accumulation. Ground all handling equipment to prevent sparking. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Storage: Store in a cool, dry place with adequate ventilation. Keep away from open flames and high temperatures. Container Warnings: Keep containers closed when not in use. Containers, even those that have been emptied, can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers. -------------------------------------------------------------------------------- SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------- Tricresyl Phosphate ACGIH TLV TWA: 0.1 mg/m3 Tricresyl phosphate OSHA PEL TWA: 0.01 mg/m3 EXPOSURE CONTROLS Adequate explosion-proof ventilation indoors and in laboratory settings to control airborne concentrations below the exposure guidelines/limits. Eye washes and showers for emergency use. PERSONAL PROTECTION Personal protective equipment (PPE) selections vary based on potential exposure conditions such as handling practices, concentration and ventilation. Information on the selection of eye, skin and respiratory protection for use with this material is provided below. Eye Protection: Chemical Goggles, or Safety glasses with side shields Skin Protection: Use protective clothing which is chemically resistant to this material. Selection of protective clothing depends on potential exposure conditions and may include gloves, boots, suits and other items. The selection(s) should take into account such factors as job task, type of exposure and durability requirements. Published literature, test data and/or glove and clothing manufacturers indicate the best protection is provided by: Butyl, or Neoprene, or Polyethylene Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134. Types of respirator(s) to be considered in the selection process include: For Mist: Air Purifying, R or P style NIOSH approved respirator. For Vapors: Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved respirator. Self-contained breathing apparatus for use in environments with unknown concentrations or emergency situations. -------------------------------------------------------------------------------- SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- Appearance & Odor: Light brown liquid. Mild odor. Substance Chemical Family: Lubricants Appearance: Light brown liquid. Flash Point: > 490 ºF [Cleveland Open Cup] Pour Point: -80 ºF Specific Gravity: 1 Viscosity: 25 cSt - 30 cSt @ 40 ºC -------------------------------------------------------------------------------- SECTION 10 REACTIVITY AND STABILITY -------------------------------------------------------------------------------- Stability: Material is stable under normal conditions. Conditions to Avoid: Avoid heat and open flames. Materials to Avoid: Avoid contact with strong oxidizing agents. Hazardous Decomposition Products: Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of airborne solids, liquids and gases will evolve when this material undergoes pyrolysis or combustion. Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides, Phosphorus Oxides and other unidentified organic compounds may be formed upon combustion. -------------------------------------------------------------------------------- SECTION 11 TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- Acute Toxicity Dermal LD50 >1 g/kg(Rabbit) OSHA: Non-Toxic Based on components(s) Oral LD50 1.25 g/kg(Rat) OSHA: Non-Toxic Based on components(s) Carcinogenicity Classification Aviation Turbine Oil NTP: No IARC: No ACGIH: No OSHA: No Neurotoxicity Multifocal spinal cord and sciatic nerve degeneration and reduced hindlimb grip strenth occurred in mice orally exposed to tricresyl phosphate for periods ranging from two weeks to two years. Reproductive Toxicity Reduced fertility was observed in both generations of mice orally exposed to tricresyl phosphate in a 2-generation reproductive effects study. The percentage of motile sperm was also signficantly reduced. In a second study of male and female rats orally exposed to TCP, males exhibited atrophy of the seminiferous tubules and aspermatogenesis. Ovarian cell hypertrophy was reported in females. Sensitization N-phenyl-1-naphthylamine was tested in guinea pigs using three different procedures. It was found to be a strong skin sensitizer in when tested by OECD guideline 406, and the Magnusson and Kligman maximumization test procedures. It was nonsensitizing when tested using the modified Landsteiner procedure. Contact dermatitis potentially associated with occupational exposure to greases or oils containing N-phenyl-1-naphthylamine and other chemicals has also been reported. Systemic Toxicity A number of organ changes were reported in rats and mice following repeated oral exposure to tricresyl phosphate. Renal papillary necrosis, cytoplasmic vacuolization in the adrenal cortex pituitary gland hypertrophy were reported in rats. Fatty liver change and necrosis of the mandibular lymph node, thymus and spleen was reported in some exposed mice. -------------------------------------------------------------------------------- SECTION 12 ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- Environmental Impact Summary: There is no ecological data available for this product. However, this product is an oil. It is persistent and does not readily biodegrade. However, it does not bioaccumulate. -------------------------------------------------------------------------------- SECTION 13 DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- RCRA Information: Under RCRA, it is the responsibility of the user of the material to determine, at the time of the disposal, whether the material meets RCRA criteria for hazardous waste. This is because material uses, transformations, mixtures, processes, etc. may affect the classification. Refer to the latest EPA, state and local regulations regarding proper disposal. -------------------------------------------------------------------------------- SECTION 14 TRANSPORT INFORMATION -------------------------------------------------------------------------------- US Department of Transportation Classification This material is not subject to DOT regulations under 49 CFR Parts 171-180. Marine Pollutant Technical Name: Tricresyl Phosphate Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500 gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also be subject to this rule. International Air Transport Association Not regulated under IATA rules. International Maritime Organization Classification Not regulated under International Maritime Organization rules. -------------------------------------------------------------------------------- SECTION 15 REGULATORY INFORMATION -------------------------------------------------------------------------------- FEDERAL REGULATORY STATUS OSHA Classification: Product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Ozone Depleting Substances (40 CFR 82 Clean Air Act): This material does not contain nor was it directly manufactured with any Class I or Class II ozone depleting substances. Superfund Amendment & Reauthorization Act (SARA) Title III: There are no components in this product on the SARA 302 list. SARA Hazard Categories (311/312): Immediate Health:YES Delayed Health:NO Fire:NO Pressure:NO Reactivity:NO SARA Toxic Release Inventory (TRI) (313): There are no components in this product on the SARA 313 list. Toxic Substances Control Act (TSCA) Status: All component(s) of this material is(are) listed on the EPA/TSCA Inventory of Chemical Substances. Other Chemical Inventories: Component(s) of this material is (are) listed on the Australian AICS, Canadian DSL, European EINECS, Korean Inventory, Philippines PICCS, State Regulation California Safe Drinking Water and Toxic Enforcement Act (Proposition 65). WARNING: This product contains a chemical(s) known to the State of California to cause birth defects or other reproductive harm. New Jersey Right-To-Know Chemical List: Tricresyl Phosphate (3130) 1 - 2.99 %weight Special Hazard -------------------------------------------------------------------------------- SECTION 16 OTHER INFORMATION -------------------------------------------------------------------------------- Revision#: 3 Revision Date: 04/20/2004 Revisions since last change (discussion): This Material Safety Data Sheet (MSDS) has been newly reviewed to fully comply with the guidance contained in the ANSI MSDS standard (ANSI Z400.1-1998). We encourage you to take the opportunity to read the MSDS and review the information contained therein. -------------------------------------------------------------------------------- SECTION 17 LABEL INFORMATION -------------------------------------------------------------------------------- READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS. PRODUCT CODE(S): 60074 AEROSHELL® Turbine Oil 560 CAUTION! May be harmful if absorbed through the skin. MAY CAUSE SKIN AND EYE IRRITATION. MAYBE HARMFUL IF SWALLOWED. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS. Refer to Section 11, Toxicological Information, for specific information on the following effects: Reproductive Toxicity Precautionary Measures: Avoid prolonged or repeated contact with eyes, skin and clothing. Avoid breathing of vapors, fumes, or mist. Do not take internally. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. FIRST AID Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue breathing or CPR as required and transport to the nearest medical facility. Skin Contact: Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment. Eye Contact: Flush eyes with large amounts of water for at least 15 minutes. If redness, burning, blurred vision or swelling persist, transport to nearest medical facility for additional treatment. Ingestion: DO NOT induce vomiting. DO NOT take internally. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Have victim rinse mouth out with water, then drink sips of water to remove taste from mouth. If the victim is coughing, choking, has shortness of breath, or difficulty breathing, transport to the nearest medical facility for additional treatment. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F, shortness of breath, chest congestion or continued coughing or wheezing. FIRE In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of water. SPILL OR LEAK Dike and contain spill. FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper disposal. CONTAINS: Synthetic ester blend with pentaerythritol, Mixture; N-Phenyl-Naphthalenamine, 90-30-2; Tricresyl phosphate (mixed isomers), 1330-78-5; Proprietary additives, Mixture NFPA Rating (Health, Fire, Reactivity): 1, 1, 0 TRANSPORTATION US Department of Transportation Classification This material is not subject to DOT regulations under 49 CFR Parts 171-180. Marine Pollutant Technical Name: Tricresyl Phosphate Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500 gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also be subject to this rule. California Safe Drinking Water and Toxic Enforcement Act (Proposition 65). WARNING: This product contains a chemical(s) known to the State of California to cause birth defects or other reproductive harm. CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flames or heat. Keep container closed and drum bungs in place. Name and Address SOPUS Products P.O. Box 4453 Houston, TX 77210-4453 ADMINISTRATIVE INFORMATION MANUFACTURER ADDRESS: SOPUS Products, P.O. Box 4453, Houston, TX. 77210-4453 Company Product Stewardship & Regulatory Compliance Contact: Timothy W Childs Phone Number: (281) 874-7708 THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS. 43390-11964-100R-04/20/2004 SHELL ENGINE OIL PRODUCTS